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Development of Photochemical Synthetic Methods with a Focus on Low Energy Light.
Development of Photochemical Synthetic Methods with a Focus on Low Energy Light.
- 자료유형
- 학위논문
- Control Number
- 0017164026
- International Standard Book Number
- 9798342744799
- Dewey Decimal Classification Number
- 547
- Main Entry-Personal Name
- Beck, Logan Rockwell.
- Publication, Distribution, etc. (Imprint
- [S.l.] : Columbia University., 2024
- Publication, Distribution, etc. (Imprint
- Ann Arbor : ProQuest Dissertations & Theses, 2024
- Physical Description
- 121 p.
- General Note
- Source: Dissertations Abstracts International, Volume: 86-05, Section: B.
- General Note
- Advisor: Rovis, Tomislav;Tekle-Smith, Makeda.
- Dissertation Note
- Thesis (Ph.D.)--Columbia University, 2024.
- Summary, Etc.
- 요약Herein is presented the doctoral research of Logan Rockwell Beck. We first report the development a library of osmium(II) polypyridyl complexes and characterize them for use in photoredox catalysis. We then report a triplet-triplet annihilation upconversion system that produces an oxidizing excited state and exhibits a remarkable 1.25 eV anti-Stokes shift. This upconversion system is then applied to dual nickel/photoredox catalyzed C-O cross-coupling. Finally, we discuss efforts towards the remote arylation of aliphatic amines through 1,5-HAT.
- Subject Added Entry-Topical Term
- Organic chemistry.
- Subject Added Entry-Topical Term
- Analytical chemistry.
- Subject Added Entry-Topical Term
- Molecular chemistry.
- Index Term-Uncontrolled
- Nickel catalysis
- Index Term-Uncontrolled
- Photoredox catalysis
- Index Term-Uncontrolled
- Spin-forbidden excitation
- Index Term-Uncontrolled
- Triplet-triplet annihilation upconversion
- Added Entry-Corporate Name
- Columbia University Chemistry
- Host Item Entry
- Dissertations Abstracts International. 86-05B.
- Electronic Location and Access
- 로그인을 한후 보실 수 있는 자료입니다.
- Control Number
- joongbu:656494
