자료유형  

 학위논문

Control Number  

0016931520

International Standard Book Number  

9798379783969

Dewey Decimal Classification Number  

541

Main Entry-Personal Name  

Lachowicz, Anton Luke.

Publication, Distribution, etc. (Imprint  

[S.l.] : Yale University., 2023

Publication, Distribution, etc. (Imprint  

Ann Arbor : ProQuest Dissertations & Theses, 2023

Physical Description  

1 online resource(100 p.)

General Note  

Source: Dissertations Abstracts International, Volume: 85-01, Section: B.

General Note  

Advisor: Johnson, Mark Albert.

Dissertation Note  

Thesis (Ph.D.)--Yale University, 2023.

Restrictions on Access Note  

This item must not be sold to any third party vendors.

Summary, Etc.  

요약The atmosphere provides a different medium than Earth's surface, with a different background of radiation as well as far from standard pressure and temperature. It can be home to unique chemical reactions. Measuring the fundamental properties of these systems is required to understand the macroscopic effects observed in the atmosphere. To obtain these measurements, gas-phase techniques such as cryogenicion spectroscopy and selected-ion, flow-tube experiments have been employed. Solution-phase and bulk gas-phase measurements suffer from difficulty isolating unique species and keeping them in uniform environments. On the other hand, cryogenic-ion spectroscopy benefits from a more uniform environment. The cryogenic temperatures (~10 - 50 K) limit the total number of states in play, which increases the precision of measurements. Selected-ion flow-tube experiments provide one of the best ways to explore the kinetic interactions of a chemical species. Together, cryogenic ion spectroscopy and selected ion flow-tube experiments provide a nearly complete picture of species' chemical interactions that can explain macroscopic phenomena. These methods were employed to determine the of the Sm + O → SmO+ + e- chemi-ionization reaction, as well as other oxygen and ozone reactions with samarium and neodymium. Ultimately, the bond dissociation energy of SmO+ was measured to be 5.596 ± 0.004 eV. This allowed for the most precise to date calculation of the thermicity of the chemiionization reaction at 0.048 ± 0.004 eV endothermic.

Subject Added Entry-Topical Term  

Physical chemistry.

Subject Added Entry-Topical Term  

Analytical chemistry.

Subject Added Entry-Topical Term  

Atmospheric sciences.

Index Term-Uncontrolled  

Cryogenic Ion spectroscopy

Index Term-Uncontrolled  

Gas-phase techniques

Index Term-Uncontrolled  

Kinetic interactions

Index Term-Uncontrolled  

Macroscopic phenomena

Index Term-Uncontrolled  

Standard pressure

Added Entry-Corporate Name  

Yale University Chemistry

Host Item Entry  

Dissertations Abstracts International. 85-01B.

Host Item Entry  

Dissertation Abstract International

Electronic Location and Access  

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Control Number  

joongbu:643824