자료유형  

 학위논문

Control Number  

0016932773

International Standard Book Number  

9798379840457

Dewey Decimal Classification Number  

600

Main Entry-Personal Name  

Wise, Patrick.

Publication, Distribution, etc. (Imprint  

[S.l.] : Purdue University., 2022

Publication, Distribution, etc. (Imprint  

Ann Arbor : ProQuest Dissertations & Theses, 2022

Physical Description  

1 online resource(122 p.)

General Note  

Source: Dissertations Abstracts International, Volume: 85-01, Section: B.

General Note  

Advisor: Ben-Amotz, Dor.

Dissertation Note  

Thesis (Ph.D.)--Purdue University, 2022.

Restrictions on Access Note  

This item must not be sold to any third party vendors.

Summary, Etc.  

요약The first two chapters make use of simple, simulated model systems to break down the unique solvation thermodynamics of solutes at the vapor-liquid interface of water and of aggregation processes in the bulk. In particular, attention is paid to the direct solutesolvent energetic and entropic components that dictate the chemical potential. This proves a fruitful approach to understanding the counter-intuitive adsorbtion of ions to the interface. Additionally, the validity of linear response theory is tested in the interfacial region. Further, the contribution of ion surface pinning to the total adsorbtion thermodynamics is explored.The third chapter studies the solvent-solvent interaction energy in response to changes in solute-solvent interactions. A solvent-solvent coupling scheme is developed to the relationship of solute-solvent interactions and solvent-solvent interactions and allows for more statistically stable access to solvent restructuring energies.The fourth chapter looks at ions of a range of sizes, but with a focus on those smaller than sodium. There smaller cations show a counter-intuitive trend of showing more attraction to the interface, when they are predicted to be more repelled than the larger ions. This is investigated with thermodynamic and hydration structure tools.

Subject Added Entry-Topical Term  

Hydrogen.

Subject Added Entry-Topical Term  

Decomposition.

Subject Added Entry-Topical Term  

Visual aids.

Subject Added Entry-Topical Term  

Energy.

Subject Added Entry-Topical Term  

Thermodynamics.

Subject Added Entry-Topical Term  

Potassium.

Subject Added Entry-Topical Term  

Solvents.

Subject Added Entry-Topical Term  

Interfaces.

Added Entry-Corporate Name  

Purdue University.

Host Item Entry  

Dissertations Abstracts International. 85-01B.

Host Item Entry  

Dissertation Abstract International

Electronic Location and Access  

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Control Number  

joongbu:643769