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Evaluating the Effects of Anthocyanin Structure and the Role of Metal Ions on the Blue Color Evolution of Anthocyanins in Varied pH Environments
ข้อมูลเนื้อหา
Evaluating the Effects of Anthocyanin Structure and the Role of Metal Ions on the Blue Color Evolution of Anthocyanins in Varied pH Environments
자료유형  
 학위논문
Control Number  
0015001355
International Standard Book Number  
9780438310063
Dewey Decimal Classification Number  
641
Main Entry-Personal Name  
Sigurdson, Gregory T.
Publication, Distribution, etc. (Imprint  
[Sl] : The Ohio State University, 2016
Publication, Distribution, etc. (Imprint  
Ann Arbor : ProQuest Dissertations & Theses, 2016
Physical Description  
199 p
General Note  
Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
General Note  
Adviser: M. Monica Giusti.
Dissertation Note  
Thesis (Ph.D.)--The Ohio State University, 2016.
Summary, Etc.  
요약Due to consumer demand and possible health concerns, the use of synthetic food colorants has been decreasing. Synthetic red and yellow colorants are most commonly used in the food industry
Summary, Etc.  
요약Acylated and nonacylated derivatives of cyanidin and delphinidin were combined with various metal ions (Mg2+, Al3+, Cr3+, Fe3+, and Ga3+) in factorial excesses to anthocyanin concentration (as large as 2000x [anthocyanin]) in pH 3-8. Phenolic ac
Summary, Etc.  
요약Anthocyanin responses to metal ion chelation were dependent on all factors tested. In all pH, anthocyanins exhibited bathochromic and hyperchromic shifts becoming more purple and blue. Largest bathochromic shifts occurred in pH 6, and largest hy
Summary, Etc.  
요약Metal chelation resulted in larger bathochromic shifts on anthocyanins with more B-ring hydroxyl groups (delphinidin cyanidin). Anthocyanins lacking acylation typically underwent much larger bathochromic shifts
Summary, Etc.  
요약Bivalent Mg2+ showed no obvious effect on anthocyanin color. Generally, bathochromic shifts on anthocyanin were greatest with more electron rich metal ions: Fe3+ . Ga3+ Al 3+ Cr3+.
Summary, Etc.  
요약Metal chelation by anthocyanins resulted in blue and purple hues similar to currently used synthetic colorants in pH environments where these colors are not typically expressed, further indicating potential to act as alternatives.
Subject Added Entry-Topical Term  
Food science
Subject Added Entry-Topical Term  
Organic chemistry
Added Entry-Corporate Name  
The Ohio State University Food Science and Technology
Host Item Entry  
Dissertation Abstracts International. 80-01B(E).
Host Item Entry  
Dissertation Abstract International
Electronic Location and Access  
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Control Number  
joongbu:557593
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