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Structure-Reactivity Relationships of Lithium Amides: LiHMDS-Mediated Enolizations of Hindered Aryl Ketones and LiTMP-Mediated Ortholithiations
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Structure-Reactivity Relationships of Lithium Amides: LiHMDS-Mediated Enolizations of Hindered Aryl Ketones and LiTMP-Mediated Ortholithiations
자료유형  
 학위논문
Control Number  
0014996838
International Standard Book Number  
9780438025660
Dewey Decimal Classification Number  
547
Main Entry-Personal Name  
Mack, Kyle Anthony.
Publication, Distribution, etc. (Imprint  
[Sl] : Cornell University, 2018
Publication, Distribution, etc. (Imprint  
Ann Arbor : ProQuest Dissertations & Theses, 2018
Physical Description  
195 p
General Note  
Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
General Note  
Adviser: David B. Collum.
Dissertation Note  
Thesis (Ph.D.)--Cornell University, 2018.
Summary, Etc.  
요약Enolizations of highly substituted acyclic ketones used in the syntheses of tetrasubstituted olefin-based anticancer agents are described. Lithium hexamethyldisilazide (LiHMDS)-mediated enolizations are moderately Z-selective in neat tetrahydro
Summary, Etc.  
요약Rate and mechanistic studies of ortholithiations by lithium 2,2,6,6-tetramethylpiperidine focus on four arenes: 1,4-bis(trifluoromethyl)benzene, 1,3-bis(trifluoromethyl)benzene, 1,3-dimethoxybenzene, and 4,4-dimethyl-2-phenyl-2-oxazoline. Metala
Subject Added Entry-Topical Term  
Organic chemistry
Subject Added Entry-Topical Term  
Chemistry
Added Entry-Corporate Name  
Cornell University Chemistry & Chemical Biology
Host Item Entry  
Dissertation Abstracts International. 79-10B(E).
Host Item Entry  
Dissertation Abstract International
Electronic Location and Access  
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Control Number  
joongbu:553270
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