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Structure-Reactivity Relationships of Lithium Amides: LiHMDS-Mediated Enolizations of Hindered Aryl Ketones and LiTMP-Mediated Ortholithiations
Structure-Reactivity Relationships of Lithium Amides: LiHMDS-Mediated Enolizations of Hindered Aryl Ketones and LiTMP-Mediated Ortholithiations
- 자료유형
- 학위논문
- Control Number
- 0014996838
- International Standard Book Number
- 9780438025660
- Dewey Decimal Classification Number
- 547
- Main Entry-Personal Name
- Mack, Kyle Anthony.
- Publication, Distribution, etc. (Imprint
- [Sl] : Cornell University, 2018
- Publication, Distribution, etc. (Imprint
- Ann Arbor : ProQuest Dissertations & Theses, 2018
- Physical Description
- 195 p
- General Note
- Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
- General Note
- Adviser: David B. Collum.
- Dissertation Note
- Thesis (Ph.D.)--Cornell University, 2018.
- Summary, Etc.
- 요약Enolizations of highly substituted acyclic ketones used in the syntheses of tetrasubstituted olefin-based anticancer agents are described. Lithium hexamethyldisilazide (LiHMDS)-mediated enolizations are moderately Z-selective in neat tetrahydro
- Summary, Etc.
- 요약Rate and mechanistic studies of ortholithiations by lithium 2,2,6,6-tetramethylpiperidine focus on four arenes: 1,4-bis(trifluoromethyl)benzene, 1,3-bis(trifluoromethyl)benzene, 1,3-dimethoxybenzene, and 4,4-dimethyl-2-phenyl-2-oxazoline. Metala
- Subject Added Entry-Topical Term
- Organic chemistry
- Subject Added Entry-Topical Term
- Chemistry
- Added Entry-Corporate Name
- Cornell University Chemistry & Chemical Biology
- Host Item Entry
- Dissertation Abstracts International. 79-10B(E).
- Host Item Entry
- Dissertation Abstract International
- Electronic Location and Access
- 로그인을 한후 보실 수 있는 자료입니다.
- Control Number
- joongbu:553270